膜
乳状液
化学工程
结垢
羧甲基纤维素
材料科学
接触角
生物污染
膜污染
色谱法
化学
复合材料
钠
生物化学
工程类
冶金
作者
Lun Ma,Yan Wan,Teng Wang,Yaling Liu,Ying Yin,Liyun Zhang
出处
期刊:Langmuir
[American Chemical Society]
日期:2022-10-04
卷期号:38 (41): 12499-12509
被引量:9
标识
DOI:10.1021/acs.langmuir.2c01905
摘要
Developing the high-anti-fouling membrane has kept continuous attention in oil/water emulsion treatment. However, the majority of works on anti-fouling membranes mainly focused on low-viscosity oils, which greatly limited the development and application of a membrane to face the real crude oil wastewater. Inspired by the hydrophilicity of sodium carboxymethyl cellulose (CMC) and zirconium base metal-organic frame (Zr-MOF), an anti-oil-fouling CMC/UiO-66-NH2 composite membrane was constructed by a self-assembly method. Profiting from the hydrophilicity and micro-nanostructure of the CMC/UiO-66-NH2 layer, the obtained CMC/UiO-66-NH2 membranes displayed underwater superoleophobicity and desired oil resistance. It could display the effective separation capability with 1282 ± 62 to 6160 ± 81 L/(m2·h·bar) and above 99.08% toward the different light oil emulsions. More importantly, the CMC/UiO-66-NH2 membrane displayed ultralow crude oil adhesion behaviors toward the crude oil emulsions, which could achieve a considerably high flux (746 ± 60 to 5224 ± 87 L/(m2·h·bar)). Furthermore, electrostatic interaction and physical enwinding-wrapping between CMC and UiO-66-NH2 also endowed the composite membranes with outstanding stability. After immersing the as-prepared membranes into the harsh environments for 24 h, the membranes still maintained high underwater-oil contact angles (UWOCA > 155°) and separation ability (oil rejection was above 99.0%). Therefore, CMC/UiO-66-NH2 composite membranes could demonstrate promising prospects in real oily emulsion treatment.
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