拉曼光谱
电介质
单斜晶系
介电常数
材料科学
分子振动
陶瓷
晶体结构
分析化学(期刊)
红外线的
红外光谱学
格子(音乐)
拉曼散射
相(物质)
凝聚态物理
化学
光学
结晶学
光电子学
物理
色谱法
复合材料
有机化学
声学
作者
Feng Shi,En-Cai Xiao,Guohua Chen,Ying Chen
标识
DOI:10.1007/s00339-020-04028-w
摘要
Non-stoichiometric Nd[Mg0.5Sn0.5(1+x)]O3 (− 0.04 ≤ x ≤ + 0.04)—type samples were prepared using a traditional two-step solid-state sintering process. Their crystal structures, phase compositions, dielectric properties and lattice vibrational characteristics were identified in detail. The double perovskite Nd(Mg0.5Sn0.5)O3 with a monoclinic structure was distinguished as the main crystalline phase, and pure phase was obtained when x < 0. The sample [Nd(Mg0.5Sn0.49)O3] at x = − 0.02 shows the excellent dielectric properties: εr = 18.74, Q × f = 47,979 GHz. The lattice vibrational characteristics were clarified with Raman and infrared active mode spectroscopy. The intrinsic properties were fitted by four-parameter semi-quantum model, which show that the low-frequency infrared modes yield a more significant contribution to permittivity and dielectric loss. Raman shifts of modes F2g(A) and F2g(B) correlate with dielectric constants negatively, which implies that the bond length has a positive correlation with permittivity. Full widths at half maximum of vibrational modes A1g(O) correlate with dielectric loss values positively and correlate with the degree of order (S) negatively.
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