季节性
环境科学
中国
大气科学
地理
物理
数学
统计
考古
作者
H. Xiao,Shiyuan Ding,Xiaodong Li
摘要
Abstract The stable nitrogen isotopic composition (δ 15 N) has been widely used to quantify sources of ammonium (NH 4 + ) in PM 2.5 . However, the overlap and uncertainty in δ 15 N values from different NH 3 sources, coupled with their seasonal variability, hinder accurate identification of NH 4 + source. Here, the δ 15 N values of various NH 3 source samples collected by the active sampler were determined. Subsequently, we measured the δ 15 N values of NH 4 + in PM 2.5 , which were collected seasonally in Tianjin. We found that the combustion‐related NH 3 (c‐NH 3 ) exhibiting higher δ 15 N values compared to volatile NH 3 (v‐NH 3 ), but all δ 15 N values was fell within the range reported by previous studies. Furthermore, inconsistent seasonal variations were observed in the δ 15 N‐NH 3 values originating from emissions of agricultural soil and human excreta. The application of the Bayesian isotope mixing model (MixSIAR model) revealed a significant increase in the contribution of v‐NH 3 to NH 4 + when incorporating current source data, as opposed to previous data, for δ 15 N of NH 3 source. Notably, the contribution of v‐NH 3 (53.1%) to NH 4 + was almost equivalent to that of c‐NH 3 (46.9%) when considering the seasonal δ 15 N signatures of NH 3 source. Additionally, the estimated contribution of v‐NH 3 to NH 4 + exhibited significant seasonal variability, which is more reasonable than in the non‐seasonal scenario. This study demonstrated that v‐NH 3 and c‐NH 3 contributed to NH 4 + in PM 2.5 in Tianjin almost equally, and it is highlighted that the seasonal δ 15 N values of NH 3 sources should be considered when estimating the contributions of different NH 3 sources to NH 4 + in PM 2.5 by the MixSIAR model.
科研通智能强力驱动
Strongly Powered by AbleSci AI