Photo-assisted “co-movement catalysis”: CoFe2O4/CNS heterojunction based portable electrochemical sensor for simultaneous detection of Pb2+ and Cd2+ in natural water

Heavy metal ions (HMIs) seriously threaten human health even under trace conditions. Therefore, accurate, efficient and simultaneous detection of multiple HMIs is of great significance. Here, a strategy of "co-movement catalysis" based on photo-assisted electrochemical catalysis is proposed by constructing a flexible electrochemical sensor with CoFe2O4/CNS heterojunction-modified nickel foam as the working electrode for simultaneous detection of HMIs. Regarding photo-assisted catalysis, CoFe2O4/CNS nanocomposites formed a p-n type heterojunction, effectively separating photo-generated electron-hole pairs and reducing photo-generated carriers' recombination rate, leading to the catalytic reaction of photogenerated electrons and holes with HMIs and atoms to improve the efficiency of preconcentration and stripping, further amplifying the electrochemical signal. Regarding electrochemical catalysis, the CoFe2O4 spinel contains variable valence transition metal ions Fe2+/Fe3+ and Co2+/Co3+, which can reduce and oxidize HMIs circularly, further enhancing the sensor's sensitivity. The portable sensor based on "co-movement catalysis" exhibited sensitive detection performance. The linear range is 0.100-10.0 μM for Pb2+ and 1.00-10.0 μM for Cd2+, with the detection limit of 0.0310 μM for Pb2+ and 0.219 μM for Cd2+, respectively. The recovery rate of the sensor to natural water samples is between 96% and 105%, which proves its development potential in environmental monitoring.