热重分析
材料科学
差示扫描量热法
天然橡胶
异戊二烯
硫化
共单体
弹性体
化学工程
米尔辛
热稳定性
极限抗拉强度
复合材料
聚合
共聚物
化学
聚合物
色谱法
热力学
物理
工程类
柠檬烯
精油
作者
Shuainan Zhao,Haijun Ji,Jie Yu,Qianqian Wang,Liqun Zhang,Runguo Wang
标识
DOI:10.1021/acs.iecr.3c01376
摘要
A series of green poly(isoprene-co-myrcene) (PIMy) elastomers were designed and prepared by coordination polymerization to solve the fossil shortage and achieve an excellent low-temperature resistance property. The properties of PIMy could be tailored upon varying the comonomer feed ratios. The structure and thermal stability were investigated by NMR, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA) analyses. The cis-1,4 structure content of PIMy exceeded 95%, and the Tg of PIMy was below −60 °C without crystallization at low temperatures. With the increase of myrcene content, the tensile strength of PIMy/silica nanocomposites decreased, the wet skid resistance was improved, and PIMy with myrcene content of 5–20 mol % had better comprehensive properties. The introduction of PIMy in solution-polymerized styrene–butadiene rubber (SSBR) increased the tan δ value at −20 °C and improved the ice skid resistance performance. The Laboratory Abrasion Tester (LAT-100) test results showed that the addition of PIMy significantly improved the friction of SSBR on the ice surface with a maximum improvement of 161%. The PIMy prepared in this study is expected to be used in low-temperature-resistant rubber products such as seals and winter tires.
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