共聚物
甲基丙烯酸酯
材料科学
高分子化学
丙烯酸酯
聚合
超分子化学
乙烯基聚合物
吡啶
溶剂
甲基丙烯酸甲酯
聚合物
化学
有机化学
复合材料
分子
作者
Nguyen Khai Hoang Nguyen,Huan Hoang Dang,Linh Hồ Thùy Nguyễn,Ly Mai Thi Nguyen,Thanh-Dat Truong,Hà Trần Nguyên,Thiet Quoc Nguyen,Chau Tran,Le‐Thu T. Nguyen
标识
DOI:10.1016/j.eurpolymj.2023.112474
摘要
For the first time hydrogen bonding complexes between poly(4-vinyl pyridine) (P4VP) and its copolymers were employed as a healing concept for building supramolecular materials with self-healability. P4VP and its random copolymers with stearyl acrylate and stearyl methacrylate were first synthesized via UV light-mediated metal-free polymerization using 4-(10H-phenothiazin-10-yl)-N,N-diphenylaniline as organic photocatalyst. Three complexes between the P4VP homopolymer and the obtained copolymers bearing “hairy” side groups with 3,3′-dithiodipropionic acid (DTDP) as a proton donor crosslinker were studied. Owing to the “solvent”-like mantle formed by lowly ordered stearyl side groups, the complex of poly(4-vinyl pyridine-random-stearyl methacrylate) and DTDP exhibited efficient self-healability of complete cuts at room temperature after 30 min, with tensile strength recovery of above 80%. The results of this work suggested that this dynamic supramolecular concept based on P4VP is promising for developing self-healing materials for various applications.
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