邻接
立体中心
废止
催化作用
分子间力
化学
组合化学
立体化学
有机化学
对映选择合成
分子
作者
Suri Babu Undamatla,K. Ramesh,N. Jagadeesh Babu,Maddi Sridhar Reddy
标识
DOI:10.1002/chem.202302788
摘要
Abstract Reaching the formidable C−H corners has been one of the top priorities of organic chemists in the recent past. This prompted us to disclose herein a vicinal annulation of 2‐iodo benzoates, indoles, and carbazoles with N‐embedded 1,6‐enynes through 7‐/8‐membered palladacycles. The relay does not require the assistance of any directing group, leading to multicyclic scaffolds, which are readily diversified to an array of adducts (with new functional tethers and/or three contiguous stereocenters), in which we showcase a rare benzylic mono‐oxygenation.
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