塔菲尔方程
析氧
过电位
高分辨率透射电子显微镜
材料科学
X射线光电子能谱
热液循环
单斜晶系
纳米材料
化学工程
水热合成
分解水
电化学
氧气
电极
纳米技术
催化作用
结晶学
晶体结构
化学
物理化学
透射电子显微镜
生物化学
光催化
工程类
有机化学
作者
Niraj Kumar,Sanjay Upadhyay,S. Chetana,Naveen Chandra Joshi,Neeraj Priyadarshi,R. Ismail Hossain,Rameshbabu,Arijit Sen
标识
DOI:10.1016/j.matlet.2022.133810
摘要
Fascination surface activities offered by nanomaterials have attracted wide attention to be used as electrode materials in oxygen evolution reactions (OER). Among various transition metal oxides (TMOs), the electrochemical behavior of one-dimensional (1D) VO2 is not explored in detail due to a lack of efficient synthesis techniques. Herein, a novel synthesis route is developed to grow fine 1D VO2 following a two-step hydrothermal reaction. XRD, XPS, EDS, SEM, and HRTEM analyses confirm the monoclinic structure of 1D VO2 with fine morphologies having diameters mostly in the range of 10–100 nm. This resulted in the attainment of best-in-class electrode material for Oxygen evolution reaction (OER). VO2 shows an excellent OER activity with a low overpotential of 626 mV at a current density of 10 mA cm−2 with a low Tafel slope of 40.4 mV dec-1. Also, it showed high cyclic stability up to 5000 cycles.
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