Electronic Localization Enables Long‐Cycling Sulfides‐Based All‐Solid‐State Lithium Batteries

/Li-In electrode display a remarkable long cycle performance with 100% retention after 1300 cycles at 0.5 C. This study presents a distinct strategy that employs the electron localization driven by modulating orbital hybridization to achieve ultrastable interface in sulfide-based all-solid-state lithium batteries.