卟啉
化学
金属有机骨架
纳米技术
光催化
分子
功能(生物学)
电催化剂
组合化学
催化作用
光化学
有机化学
材料科学
物理化学
电化学
电极
吸附
生物
进化生物学
作者
Xuan Zhang,Megan C. Wasson,Mohsen Shayan,Ellan K. Berdichevsky,Joseph Ricardo-Noordberg,Zujhar Singh,Edgar K. Papazyan,Anthony J. Castro,Paola Marino,Zvart Ajoyan,Zhijie Chen,Timur İslamoğlu,Ashlee J. Howarth,Yangyang Liu,Marek B. Majewski,Michael Katz,Joseph E. Mondloch,Omar K. Farha
标识
DOI:10.1016/j.ccr.2020.213615
摘要
Porphyrins are important molecules widely found in nature in the form of enzyme active sites and visible light absorption units. Recent interest in using these functional molecules as building blocks for the construction of metal–organic frameworks (MOFs) have rapidly increased due to the ease in which the locations of, and the distances between, the porphyrin units can be controlled in these porous crystalline materials. Porphyrin-based MOFs with atomically precise structures provide an ideal platform for the investigation of their structure–function relationships in the solid state without compromising accessibility to the inherent properties of the porphyrin building blocks. This review will provide a historical overview of the development and applications of porphyrin-based MOFs from early studies focused on design and structures, to recent efforts on their utilization in biomimetic catalysis, photocatalysis, electrocatalysis, sensing, and biomedical applications.
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