异质结
光催化
制氢
石墨氮化碳
材料科学
分解水
肖特基势垒
半导体
催化作用
氢
光催化分解水
氢燃料
太阳能燃料
化学工程
纳米技术
光电子学
化学
有机化学
二极管
工程类
生物化学
作者
Haiying Xu,Rong Xiao,Jingran Huang,Yan Jiang,Chengxiao Zhao,Xiaofei Yang
出处
期刊:Chinese Journal of Catalysis
[China Science Publishing & Media Ltd.]
日期:2021-01-01
卷期号:42 (1): 107-114
被引量:147
标识
DOI:10.1016/s1872-2067(20)63559-8
摘要
Converting sustainable solar energy into hydrogen energy over semiconductor-based photocatalytic materials provides an alternative to fossil fuel consumption. However, efficient photocatalytic splitting of water to realize carbon-free hydrogen production remains a challenge. Heterojunction photocatalysts with well-defined dimensionality and perfectly matched interfaces are promising for achieving highly efficient solar-to-hydrogen conversion. Herein, we report the fabrication of a novel type of protonated graphitic carbon nitride (PCN)/Ti3C2 MXene heterojunctions with strong interfacial interactions. As expected, the two-dimensional (2D) PCN/2D Ti3C2 MXene interface heterojunction achieves a highly improved hydrogen evolution rate (2181 μmol·g−1) in comparison with bulk g-C3N4 (393 μmol·g−1) and protonated g-C3N4 (816 μmol·g−1). The charge-regulated surfaces of PCN and the accelerated charge transport at the face-to-face 2D/2D Schottky heterojunction interface are the major contributors to the excellent hydrogen evolution performance of the composite photocatalyst.
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