Enhancing the stability and combustion of a nanofluid fuel with polydopamine-coated aluminum nanoparticles

煤油 燃烧 纳米流体 材料科学 涂层 点火系统 结块 化学工程 纳米颗粒 复合材料 纳米技术 化学 有机化学 热力学 物理 工程类
作者
Wen Ao,Yi Gao,Shuai Zhou,Larry K.B. Li,Wei He,Peijin Liu,Qi‐Long Yan
出处
期刊:Chemical Engineering Journal [Elsevier BV]
卷期号:418: 129527-129527 被引量:46
标识
DOI:10.1016/j.cej.2021.129527
摘要

In this experimental study, we examine the stability and combustion of a new nanofluid fuel created by mixing kerosene and nano-aluminum (n-Al) particles coated with polydopamine (PDA). Focus is placed on examining the effect of the PDA coating time, and hence the PDA film thickness, with the aid of a proposed heat transfer mechanism for the combustion of [email protected]/kerosene droplets. The results indicate that [email protected](1 h)/kerosene (i.e. a PDA coating time of one hour), which remains stable for seven hours, exhibits better stability than all the other samples, but that the stability worsens as the PDA coating time increases. The ignition character of n-Al/kerosene nanofluid droplets is not quite sensitive to PDA layer. The combustion processes of n-Al/kerosene and [email protected]/kerosene are remarkably similar, consisting of four distinct stages: ignition, classic combustion, vapor flame extinguishing, and Al droplet combustion. The burning intensity of n-Al agglomerates coated with PDA is stronger than that without PDA, with more black smoke generated and more n-Al particles expelled near the end of the n-Al burning stage. The combustion rates of kerosene droplets containing 5% [email protected](1 h) and 5% [email protected](2 h) are higher than other samples. The intensity of the emission spectra for the [email protected](2 h) agglomerates is the highest among all the samples. Taken together, these results indicate that, compared with uncoated n-Al/kerosene and other PDA-coated nanofluid fuels, [email protected](2 h)/kerosene exhibits superior ignition and combustion characteristics, opening new possibilities for tailoring Al-based nanofluid fuels.

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