吸附
戊二醛
离子强度
化学
水溶液
腐植酸
蒸馏水
弗伦德利希方程
膜
核化学
色谱法
扩散
无机化学
有机化学
物理
热力学
生物化学
肥料
作者
Jian Hua Chen,Qing Lin Liu,Shi Rong Hu,Jian Ni,Ya Shan He
标识
DOI:10.1016/j.cej.2011.08.023
摘要
A novel porous composite membrane adsorbent GA-HA/SA was prepared by glutaraldehyde (GA) crosslinked humic acid (HA) immobilized sodium alginate (SA) and used to remove Cu(II) ions from wastewater. Compared with traditional centrifugation or filtration methods for separating adsorbent from solution, the Cu-HA/SA can be used more conveniently. The physico-chemical properties of GA-HA/SA before and after adsorption were investigated by FT-IR, SEM and EDX methods. To investigate the effects of experimental parameters on adsorption behavior, a batch of experiments were performed by changing the concentration of porogen polyethylene glycol in the GA-HA/SA, solution pH, ionic strength, initial Cu(II) ions concentration and contact time. The GA-HA/SA showed the maximum uptake of 63.1 mg/g under the optimal adsorption condition. Based on adsorption experiment, it can be found that uptake capacity of the GA-HA/SA for Cu(II) ions decreased with an increasing of ionic strength, and solution pH decreased until the adsorption equilibrium. Kinetics experiments indicated the pseudo-second-order model displayed the best correlation with adsorption kinetics data. The Crank model showed that the intraparticle solute diffusion is the rate-controlling adsorption step. Besides, adsorption experimental data could be better described by the Freundlich isotherm model.
科研通智能强力驱动
Strongly Powered by AbleSci AI