A Facile Route to Aryl Boronates: Room‐Temperature, Copper‐Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

A simple but effective copper-catalyzed borylation of aryl halides, including electron-rich and sterically hindered aryl bromides, with alkoxy diboron reagents occurs under mild conditions (see scheme). Preliminary DFT studies of the mechanism suggest that sigma-bond metathesis between a copper-boryl intermediate and the aryl halide generates the aryl boronate product.