材料科学
阳极
电催化剂
氧化物
化学工程
固体氧化物燃料电池
氧化钇稳定氧化锆
复合数
合金
碳纤维
图层(电子)
复合材料
冶金
立方氧化锆
电极
电化学
陶瓷
化学
物理化学
工程类
作者
Massimiliano Lo Faro,Rafael M. Reis,G. G. A Saglietti,Vanessa L. Oliveira,Sabrina Campagna Zignani,Stefano Trocino,Susanna Maisano,Édson Antônio Ticianelli,Nejc Hodnik,Francisco Ruiz-Zepeda,A.S. Aricò
标识
DOI:10.1016/j.apcatb.2017.08.010
摘要
Solid oxide fuel cells (SOFCs) based on conventional nickel-yttria stabilised zirconia (Ni-YSZ) anodes can not be fed directly with organic fuels because of the associated formation of carbon deposits. This work explores a simple approach to solve such relevant limiting factor that affects the direct utilization of conventional dry hydrocarbons in SOFCs. The approach consists in depositing a composite multifunctional electrocatalyst layer on the SOFC anode to work as an internal integrated fuel processor. This study investigates the direct oxidation of dry ethanol in the modified SOFC and provides an evaluation of cell performance. A protective layer based on a composite made of Ni-modified perovskite and gadolinia-doped ceria is coated on a conventional SOFC anode based on Ni-YSZ. Besides the oxygen storage properties of ceria, the composite electrocatalyst is characterized by the presence of dispersed Ni-alloy @ FeOx core-shell nanoparticles in the outer layers and surface basicity properties. Efficient dehydrogenation of ethanol, carbon deposition-free cracking reactions and internal reforming assisted by a H2/H2O “shuttle mechanism” appear as the key steps involved in the direct oxidation of the organic fuel at the modified SOFC anode. The best performance achieved for the dry ethanol-fed SOFC is about 0.65 W cm−2 at 0.6 V and 800 °C. No carbon deposition is observed both on the Ni-YSZ supporting layer and protective Ni-doped perovskite layer after a durability test of more than 100 h.
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