材料科学
碳纳米泡沫
超级电容器
复合材料
电解质
电极
活性炭
电容
介孔材料
碳纤维
多孔性
复合数
吸附
化学
有机化学
物理化学
生物化学
催化作用
作者
Xun Zhang,Zhonglin Bu,Rui Xu,Bing Xie,Hongyi Li
标识
DOI:10.1142/s1793604717500771
摘要
Electrode materials with high performance and low cost are demanding in supercapacitor applications. Novel V 2 O 3 nanofoam@activated carbon composites have been prepared simply and cost-efficiently. Due to the mesoporous structure and high specific surface of V 2 O 3 nanofoam and the good electric conductivity of activated carbon, the obtained composites exhibit an obviously improved specific capacitance as high as 185[Formula: see text]F/g, which overpasses bulk V 2 O 3 (119[Formula: see text]F/g) and activated carbon (113[Formula: see text]F/g). The rate capability of V 2 O 3 nanofoam@activated carbon composites has also been improved, owing to the increased electron transport accelerated by the activated carbon and the fast electrolyte ion intercalation/deintercalation facilitated by mesopores of V 2 O 3 nanofoam. The composites retain 56% of initial specific capacitance when the current density increases from 0.05[Formula: see text]A/g to 1.0[Formula: see text]A/g. Therefore, the obtained V 2 O 3 nanofoam@activated carbon composites are low-cost electrode materials with obviously improved electrochemical performance, which are idea for supercapacitor application.
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