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Characterization of Hydrogen Diffusion in Offshore Steel S420G2+M Multi-layer Submerged Arc Welded Joint

材料科学 焊接 扩散 母材 接头(建筑物) 冶金 埋弧焊 海上风力发电 复合材料 开裂 电弧焊 结构工程 涡轮机 机械工程 热力学 有机化学 化学 工程类 物理
作者
Michael Rhode,Jonathan Nietzke,Tobias Mente,Tim Richter,Thomas Kannengießer
出处
期刊:Journal of Materials Engineering and Performance [Springer Nature]
卷期号:31 (9): 7018-7030 被引量:9
标识
DOI:10.1007/s11665-022-06679-7
摘要

Abstract As onshore installation capacity is limited, the increase in the number of offshore wind turbines (OWT) is a major goal. In that connection, the OWTs continuously increase in size and weight and demand adequate foundations concepts like monopiles or tripods. These components are typically manufactured from welded mild steel plates with thickness up to 200 mm. The predominant welding technique is submerged arc welding (SAW). In accordance with the standards, the occurrence of hydrogen-assisted cracking is anticipated by either a minimum waiting time (MWT, before non-destructive testing of the welded joint is allowed) at ambient or a hydrogen removal heat treatment (HRHT) at elevated temperatures. The effectiveness of both can be estimated by calculation of the diffusion time, i.e., diffusion coefficients. In this study, these coefficients are obtained for the first time for a thick-walled S420G2+M offshore steel grade and its multi-layer SAW joint. The electrochemical permeation technique at ambient temperature is used for the determination of diffusion coefficients for both the base material and the weld metal. The coefficients are within a range of 10 −5 to 10 −4 mm 2 /s (whereas the weld metal had the lowest) and are used for an analytical and numerical calculation of the hydrogen diffusion and the related MWT. The results showed that long MWT can occur, which would be necessary to significantly decrease the hydrogen concentration. Weld metal diffusion coefficients at elevated temperatures were calculated from hydrogen desorption experiments by carrier gas hot extraction. They are within a range of 10 −3 mm 2 /s and used for the characterization of a HRHT dwell-time. The analytical calculation shows the same tendency of long necessary times also at elevated temperatures. That means the necessary time is strongly influenced by the considered plate thickness and the estimation of any MWT/HRHT via diffusion coefficients should be critically discussed.

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