材料科学
铁电性
薄膜
结晶度
退火(玻璃)
电容器
极化(电化学)
电极
光电子学
氧气
复合材料
纳米技术
电压
电介质
电气工程
工程类
物理化学
有机化学
化学
作者
Hyo‐Bae Kim,Kyun Seong Dae,Youkyoung Oh,Seung‐Won Lee,Yoseop Lee,Seung‐Eon Ahn,Jae Hyuck Jang,Ji‐Hoon Ahn
标识
DOI:10.1002/admi.202102528
摘要
Abstract Fluorite‐structure ferroelectric thin films have been extensively studied as promising candidates for next‐generation non‐volatile memory. However, these ferroelectric thin films have fatal issues such as the irregular formation of the ferroelectric phase, low cycling endurance, and wake‐up and fatigue during endurance cycling tests. These problems are reportedly caused by oxygen vacancies, which form due to the interface reaction between the thin films and bottom electrodes during deposition and the post‐annealing process. Therefore, in this work, the enhanced ferroelectric characteristics of Hf 1‐x Zr x O 2 thin films that control the oxygen vacancies in thin films through interfacial pretreatment are investigated. Interfacial treatment using an oxygen source can reduce oxygen vacancies and improve crystallinity through intentional oxidation of the bottom electrode. As a result, the remanent polarization value is increased by ≈1.6 times by applying the optimized pretreatment condition, and the measured 2 P r is a very high value of 73 µC cm −2 . Furthermore, it exhibits very stable ferroelectric properties without a wake‐up effect or significant fatigue, up to 10 8 cycles even under a severe electric field of 3.5 MV cm −1 . This simple strategy provides a new avenue to effectively improve the performance and cycling endurance of devices with ferroelectric thin films.
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