镝
羧酸盐
草酸盐
化学
氢键
结晶学
三角晶系
三角棱镜分子几何学
离子
分子
无机化学
立体化学
晶体结构
八面体
有机化学
作者
Chun‐De Huang,Jie-Xuan Huang,Yiyi Wu,Ying-Yang Lian,Ronghua Zeng
标识
DOI:10.1107/s1600536809000580
摘要
In the title complex, {[Dy(C(6)H(4)NO(3))(C(2)O(4))(H(2)O)]·H(2)O}(n), the Dy(III) ion is coordinated by seven O atoms from two 2-oxidopyridinium-3-carboxylate ligands, two oxalate ligands and one water mol-ecule, displaying a distorted bicapped trigonal-prismatic geometry. The carboxyl-ate groups of the 2-oxidopyridinium-3-carboxylate and oxalate ligands link dysprosium metal centres, forming layers parallel to (100). These layers are further connected by inter-molecular O-H⋯O hydrogen-bonding inter-actions involving the coordin-ated water mol-ecules, forming a three-dimensional supra-molecular network. The uncoordinated water mol-ecule is involved in N-H⋯O and O-H⋯O hydrogen-bonding inter-actions within the layer.
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