Full biomass-based multifunctional flocculant from lignin and cationic starch

Flocculation is a common process for wastewater treatment. However, the most commonly used organic synthetic flocculants such as polyacrylamide are difficult to biodegrade. In this work, biomass lignin was grafted with cationic starch to synthesize low-cost, green and fully biomass-based multifunctional flocculants. The cationic polyacrylamide was replaced by cheap industrial cationic starch. Hyperbranched multifunctional lignin-grafted cationic starch flocculant (CS-L) was successfully prepared via ring-opening reaction with epichlorohydrin. The mass content of lignin in the grafted product was between 16.6 % and 70.1 %. With the dosage of CS-L between 4.0 and 7.5 mg/L, the turbidity removal rate for 500 mg/L kaolin suspension reached more than 97 %. When the dosage of CS-L was 24 mg/L, the removal rate of 50 mg/L Cu2+ reached 85.7 %. Importantly, when the mixed solution of kaolin particles and Cu2+ was treated, the synchronous removal rates of kaolin and Cu2+ reached 90 % and 72 % respectively in the range of 8.0–12.0 mg/L flocculant addition. The synthesized lignin-grafted cationic starch flocculant showed an excellent multifunctional flocculation function.