Highly Efficient Cauliflower-like Palladium-Loaded Porous MOF as a Robust Material for the Degradation of Organic Dyes

A series of porous MOF materials, viz., Pd_x@IRMOF-9 (x = 2, 5, and 10%) were synthesized by loading varying concentrations of Pd(II) on IRMOF-9. The synthesized MOF materials were characterized by ltravioletisible (UV-Vis) spectroscopy, Fourier transform Infrared (FT-IR) spectroscopy, powder X-ray diffraction (PXRD), Brunauer-Emmett-Teller (BET), and scanning electron microscopy (SEM) analyses. UV, FT-IR, and PXRD data of Pd(II)@IRMOF-9 were found to be in line with those of IRMOF-9, which suggests that the structure of the IRMOF-9 remained intact upon Pd(II) loading. Surface morphology of IRMOF-9 showed sheet-like structures, and upon incorporation of Pd(II) to IRMOF-9, porous cauliflower-shaped MOFs were obtained. The SEM area mapping of Pd_10%@IRMOF-9 confirmed the homogeneous dispersion of Pd(II) on IRMOF-9. BET measurements suggested an increase in the surface area as well as pore size upon incorporation of Pd(II) on IRMOF-9. Due to high porosity and high petal density, Pd_10%@IRMOF-9 demonstrated degradation of seven organic dyes, namely, orange G, methylene blue, methyl orange, congo red , methyl red, rhodamine 6G, and neutral red. It showed excellent results with >90% dye degradation efficiency in case of cationic, anionic as well as neutral dyes. Degradation of organic dyes followed the pseudo-first-order kinetics. Kinetic parameters, K_M and V_max, were calculated using the double reciprocal Lineweaver-Burk plot and were found to be 13.2 μM and 26.68 × 10^-8 M min^-1, respectively. Recyclability studies of heterogeneous Pd_10%@IRMOF-9 demonstrated the degradation of CR dye for five consecutive cycles without significant loss of its catalytic activity. Herein, a robust and efficient material for the degradation of organic dyes has been developed and demonstrated.