Coordination of Pt(IV) by {P8W48} Macrocyclic Inorganic Cavitand: Structural, Solution, and Electrochemical Studies

Hydrothermal reaction of a macrocyclic inorganic POM cavitand Li₁₇(NH₄)₂₁H₂[P₈W₄₈O₁₈₄] with [Pt(H₂O)₂(OH)₄] results in coordination of up to six {Pt(H₂O)_x(OH)_4-x} fragments to the internal surface of the polyoxoanion. The product was isolated as K₂₂(NH₄)₉H₃[{Pt(OH)₃(H₂O)}₆P₈W₄₈O₁₈₄]·79H₂O (1) and characterized by multiple techniques in the solid state (SCXRD, XRPD, XPS, FTIR, and TGA) and in solution (NMR, ESI-MS, and HPLC-ICP-AES). Electrochemical properties were studied both in solution and as components of the paste electrode. The complex shows electrocatalytic activity in water oxidation.