超级电容器
层状双氢氧化物
材料科学
电容
电化学
化学工程
介孔材料
氢氧化物
电极
储能
纳米技术
比表面积
化学
有机化学
催化作用
工程类
物理化学
功率(物理)
物理
量子力学
作者
Guiquan Liu,Guorong Wang,Xin Guo,Xuqiang Hao,Kai Wang,Zhiliang Jin
标识
DOI:10.1002/ente.202200809
摘要
The charge conductivity properties and ionic delivery of pseudocapacitive materials are important factors for the charge storage process. Herein, the new petal-like S-NiV-layered double hydroxide (LDH) materials are successfully synthesized by a presynthetic solvothermal reaction and a sulfidation modification procedure. The specific capacitance of the new petal-like S-NiV-LDHs electrode reaches 1403 F g−1 when the current density is 1 A g−1, and this is attributed to Ni3S2 formed on the surface of NiV-LDHs. When the current density is up to 20 A g−1, the rate performance of the new petal-like S-NiV-LDHs electrode is 65.04%. It can be seen that the comprehensive electrochemical performance of the new petal-like S-NiV-LDHs is better than the petal-like NiV-LDHs before modification. When the power density of the S-NiV-LDHs//activated carbon asymmetric supercapacitor cell is 2278.48 W kg−1, its energy density is 20 Wh kg−1. The innovation of this work lies in that, based on the microstructure of petal-like NiV-LDHs with rich mesoporous structure, the surface of petal-like NiV-LDHs is slightly sulfurized, which makes the new petal-like S-NiV-LDHs electrode material have smaller electrochemical impedance, richer oxidation states, richer chemical active sites, better energy storage, and cycle stability.
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