电解质
电化学
离子电导率
锂(药物)
材料科学
季戊四醇
离子液体
丁二腈
聚合物
快离子导体
玻璃化转变
化学工程
三羟甲基丙烷
高分子化学
电极
化学
复合材料
聚氨酯
工程类
有机化学
催化作用
物理化学
阻燃剂
内分泌学
医学
作者
Yaser Almazrou,Thein Kyu
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2022-11-15
卷期号:4 (12): 9417-9429
被引量:4
标识
DOI:10.1021/acsapm.2c01698
摘要
A copolymer network consisting of poly(trimethylolpropane ethoxylate triacrylate) oligomer (TMPETA) and pentaerythritol tetrakis (3-mercaptopropionate) cross-linker (PETMP, tetrathiol) was photo-cross-linked via “thiol–ene click” reaction. The conetwork (TMPETA-co-PETMP) exhibited a single glass transition temperature (Tg) shifting systematically to a lower temperature with increasing content of tetrathiol cross-linker from −22 °C at 100:0 to −36 °C at the composition of 60:40 ratio by weight %. Polymer electrolyte membranes (PEMs) containing various contents of lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) salt and succinonitrile (SCN) plasticizer were investigated in order to obtain optimum PEM formulation having high ionic conductivity and good mechanical support for use in lithium metal batteries. The optimized PEM composition of (70:30) 20/40/40 (TMPETA-co-PETMP)/SCN/LiTFSI exhibited high room-temperature ionic conductivity of ∼1.8 × 10–3 S/cm, good mechanical performance, and high Li+ transference number of ∼0.76 suggestive of domination by the lithium cation transport, which would alleviate some drawbacks encountered in conventional liquid electrolyte systems. Moreover, the PEM was found to be electrochemically stable up to 5.3 V with excellent cyclability. The specific capacity of 147 mA h g–1 was obtained at 0.1 C from the Li-PEM-LFP cell, exhibiting excellent capacity retention of about 94%. Given the excellent ionic conductivity at ambient, good mechanical integrity, thermal stability, and outstanding electrochemical performance at various operating conditions, the present all-solid-state PEM is an excellent candidate for potential application in high-energy lithium metal batteries.
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