石墨烯
两亲性
皮克林乳液
乳状液
催化作用
化学
氧化物
污染物
危险废物
水溶液
化学工程
石油泄漏
有机化学
材料科学
废物管理
纳米技术
环境科学
共聚物
环境工程
聚合物
工程类
作者
Hongbing Dan,Yue Gao,Lidong Feng,Weiyan Yin,Xing Xu,Baoyu Gao,Qinyan Yue
标识
DOI:10.1016/j.jhazmat.2022.130469
摘要
Oil fractions containing highly toxic and hazardous organic contaminants can not only cause severe environmental disasters, but also an undesired waste of resources. Given the exceptional performance of persulfates in the removal of persistent and refractory organic pollutants from aqueous media, herein, a peroxymonosulfate-based Pickering emulsion catalytic (PPEC) system was constructed for the hazardous oil purification, using super-amphiphilic graphene as a solid emulsifier and a heterogeneous catalyst simultaneously. Combined detailed instrumental analysis with theoretical calculations, we find that the incorporation of pyridinic N and its oxide significantly facilitated the formation of super-amphiphilic graphene and successfully induced the formation of Pickering emulsion. In addition to stabilizing the PPEC system, super-amphiphilic graphene can also achieve efficient removal of Sudan III (simulated lipophilic organic pollutant) by activating peroxymonosulfate (PMS) to generate •O2- and 1O2. Results showed that 80 mg/L Sudan III (20 mL) could be fully degraded within 30 min using 10 mL 5 mmol PMS. More significantly, our proposed PPEC system also exhibited excellent property in the purification of practical waste engine oil. This study provides new insights into the purification and recovery of waste oil.
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