Electrolyte Design and Optimization for Alkali Metal‐Sulfur Batteries

Abstract Alkali metal‐sulfur batteries, including lithium‐sulfur (Li‐S), sodium‐sulfur (Na‐S), and potassium‐sulfur (K‐S) systems, have garnered significant attention as promising electrochemical energy storage (EES) technologies. Among them, Li‐S batteries stand out as strong contenders for next‐generation energy storage, owing to their high energy density and the cost‐effectiveness of sulfur‐based cathodes. However, with the rapid technological advances and the escalating energy demand, lithium resources are becoming increasingly scarce, making it imperative to explore alternative metal anodes to replace lithium. Therefore, Na‐S and K‐S batteries, serving as counterparts to Li‐S systems, are emerging as formidable contenders for next‐generation energy storage technologies due to the abundant and cost‐effective nature of sodium and potassium. Although Na‐S and K‐S batteries possess considerable potential in the energy sector, their development is still in its infancy, with performance constrained by the nascent state of electrolyte design and optimization. This review article provides a comprehensive overview of recent advancements and developments in liquid electrolytes for alkali metal‐sulfur batteries. Additionally, it identifies key challenges and proposes future research directions aimed at enhancing electrolyte stability, optimizing interfacial compatibility, and improving the overall performance of alkali metal‐sulfur batteries.