In-situ synthesized 2D MXene/TiO2/Fe hybrid with (001)–(101) surface heterojunction for degradation of tetracycline under visible light

Tetracycline (TC) as a common antibiotic has adverse effects on human healthy and biological survival. In this study, a novel MXene/TiO2/Fe hybrid was designed and successfully synthesized by combination method of calcination and hydrothermal reduction. The photocatalysts were characterized by PXRD, SEM, TEM, VSM and XPS, etc. It was found that MXene/TiO2/Fe exhibited 2D multilayer structure like MXene. The in-situ synthesized TiO2 through calcinating MXene exhibited an octahedral biconical structure with exposed (001) and (101) facets. Surface heterojunction of (001) and (101) facets was formed within TiO2, which enhanced the separation of photogenerated electrons and holes. The residual MXene could play a role in co-catalyst to capture the photo-generated electrons from TiO2. Moreover, Fe nanoparticles not only optimize the band gap structure and increase the specific surface area, but also store the electrons as a good electrons acceptor, which further promote the separation of electrons and holes. The TC removal efficiency of optimal MXene/TiO2/Fe could reach 92% within 120 min. Moreover, the influence of external environment factors such as pH, catalyst dosages and common anions were investigated in detail. Mechanism analysis show that h+, •OH and •O2− are the main active substances. Finally, the degradation pathways were proposed according to LC-MS.