石墨烯
材料科学
兴奋剂
分解
吸附
六氟化硫
纳米技术
表征(材料科学)
基质(水族馆)
化学物理
化学工程
光电子学
化学
物理化学
海洋学
有机化学
地质学
工程类
作者
Hong Liu,Weigen Chen,Zhixian Zhang,Hong Tian,Tianyi Sang,Kaijie Wu,Zijie Tang
标识
DOI:10.1016/j.apsusc.2023.157630
摘要
SF6 gas will decompose four characteristic decomposition products (H2S, SO2, SO2F2 and SOF2) when an insulation failure occurs early in SF6 gas-insulated equipment. By building gas-sensitive sensors into insulation devices it is possible to detect the characteristic gases of insulation faults. In this paper, we use Graphene which is available with good gas sensitivity, as a substrate and then improve the gas response of Graphene by doping with TiO2 clusters. The adsorption mechanism of (TiO2)n-Graphene (n = 1–4) on four characteristic decomposition gases is firstly analyzed based on first principles, and then verifies experimentally. (TiO2)n-Graphene (n = 1–4) shows the largest change in Eg after adsorption of SO2 gas with 61.70%, 1.07%, 23.19% and 64.04%, respectively. The SEM characterization shows that Graphene has an obvious lamellar structure, and TiO2 nanoparticles are mainly distributed on the outer wall of Graphene, which has a large curvature and strong surface activity. The gas-sensitive response values of the (TiO2)n-Graphene (n = 1–4) sensor for different gases at the same gas concentration are ranked as SO2 > H2S > SO2F2 > SOF2. The results show that TiO2 cluster-doped Graphene is a potential gas-sensitive sensing material that can be a new material for online monitoring of faulty gas content in SF6 gas-insulated equipment.
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