油页岩
热解
萃取(化学)
化学
地质学
矿物学
色谱法
有机化学
古生物学
作者
Jingjing Gu,SunhuaDeng,Huafei Fu,Dongxue Yu,Weidong Tang,Youhong Sun,Wei Guo,Weiguang Shi
出处
期刊:Fuel
[Elsevier]
日期:2024-05-01
卷期号:364: 131064-131064
标识
DOI:10.1016/j.fuel.2024.131064
摘要
Sub-critical water extraction is being considered as a potential in-situ conversion process for deep-lying oil shale. In this study, low-grade oil shale cores from the Nong’an oil shale in-situ conversion pilot were extracted by sub-critical water at 350 °C for 5–100 h. The results show that the maximum oil yield obtained at 50 h was 3.68 %, higher than the 3.45 % yield from Fischer assay analysis. It shows that sub-critical water extraction can obtain more organic matter than retorting. Additionally, a large amount of bitumen remained in the shale matrix after sub-critical water extraction. Its content reached maximum value when the kerogen was completely cracked at about 70 h. The gas chromatography-mass spectrometry (GC–MS) was conducted to analyze the components of the shale oil and residual bitumen. The results showed that n-alkanes, iso-hydrocarbons, aromatics, and n-alkenes were the major components of the kerogen cracking products. More aliphatic hydrocarbons could be extracted by sub-critical water, but more heteroatomic compounds would remain in the shale residue. This illustrates the selective extraction of more aliphatic hydrocarbons by sub-critical water during hydrolysis. The solid-state 13C NMR results of kerogen indicated that, under the action of sub-critical water, the long aliphatic chain in kerogen could be easily pyrolysis and released. The condensation of aromatic carbons was inhibited during the cracking of kerogen. The X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) analysis revealed that, some sulfur-containing functional groups would be oxidized or cyclized to sulfone and thiophene, and some oxygen-containing components might form hydroxyl and oxy heterocycle after cracking in sub-critical water. Anyway, sub-critical water extraction can more effectively present the in-situ conversion process.
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