One Droplet toward Efficient Alcohol Detection Using Femtosecond Laser Textured Micro/Nanostructured Surface with Superwettability

Abstract Alcohol with different concentrations is commonly used in food, industry, and medicine fields all over the world. However, current methods for detecting alcohol concentration are restricted to large sample consumption, additional senergy consuming, or complex operations. Here, inspired by superwettability of lotus leaves, a superhydrophobic and superorganophilic surface is designed on the polydimethylsiloxane (PDMS) for one droplet efficient alcohol detection, which is prepared via femtosecond laser direct writing technology. Meanwhile, the contact angles of droplets with various alcohol concentrations on the laser‐treated PDMS (LTP) surface are different. Based on the above characteristic, alcohol concentration through contact angle measurement without any external energy is directly detected, which is simple and efficient. Furthermore, it is worth noting that the LTP surface remains stable wettability after 1000 water–ethanol cycles and 300 days tests in air, indicating strong surface repeatability and stability. Significantly, the LTP surface has a broad potential application in one droplet detecting alcohol concentration, fake or genuine wine, and alcohol molecules. This work provides a new strategy to fabricate a superwetting surface for efficient one droplet alcohol detection.