检出限
化学
荧光
纳米化学
Mercury(编程语言)
自来水
光化学
量子点
核化学
线性范围
焦磷酸盐
分析化学(期刊)
无机化学
纳米探针
材料科学
纳米技术
色谱法
有机化学
环境工程
量子力学
物理
工程类
计算机科学
酶
程序设计语言
作者
Qianqian Duan,Xiaoyuan Wang,Boye Zhang,Yi Li,Wendong Zhang,Yixia Zhang,Shengbo Sang
标识
DOI:10.1007/s00604-019-3872-0
摘要
Pyrophosphate-modified carbon quantum dots (PP-CDs) are demonstrated to be a viable fluorescent nanoprobe for mercury(II) (Hg2+) detection. Hg2+ reacts with the pyrophosphate groups on the surface of PP-CDs to form a non-fluorescent complex. This results in quenching of the green fluorescence which has excitation/emission peaks at 400/513 nm. Static quenching is shown to be the dominant mechanism. The probe works in 0.1 μM to 1.4 μM Hg2+ concentration range, and the limit of detection is 2 nM. The PP-CDs were also used to visualize Hg2+ inside human hepatocyte LO2 cells.
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