Ni-Catalyzed asymmetric hetero-Diels–Alder reactions of conjugated vinyl azides: synthesis of chiral azido polycycles

We report herein an efficient Ni(ii)/Feng ligand-catalyzed asymmetric hetero-Diels–Alder reaction between conjugated vinyl azides with carbonyl groups, providing a synthesis of complicated chiral azido polycycles in high yields and excellent enantioselectivities.