吸附
氟化物
吸热过程
地下水
弗伦德利希方程
化学
碳酸钙
溶解
流出物
碱度
降水
核化学
无机化学
地质学
环境工程
有机化学
环境科学
物理
气象学
岩土工程
作者
Zhao Wang,Junfeng Su,Xiaofen Hu,Amjad Ali,Zizhen Wu
标识
DOI:10.1016/j.jhazmat.2020.124748
摘要
Biosynthetic crystals (BC) were prepared through microbially induced calcium carbonate precipitation (MICP) for fluoride (F−) removal from the groundwater. Batch experiments were conducted to evaluate the fluoride adsorption capacity and the impacts of critical factors (organic matter, pH, initial fluoride concentration and BC dosage) on defluorination efficiency of BC. The maximum adsorption amount and defluorination efficiency were recorded as 5.10 mg g−1 and 98.24%, respectively. The adsorption kinetics and isotherms studies showed that pseudo-second-order kinetic model and Freundlich isotherm model were best fitting to the reaction. Adsorption thermodynamic parameters indicated a spontaneous, endothermic and thermodynamically favorable adsorption process. Moreover, the mechanism of F− removal by BC was further analyzed by SEM, XPS, XRD and FTIR. The method can cope with the problem of applying the external organic substances in MICP, and avoid the microbial safety risk in the effluent. As an economically and environmentally friendly adsorbent, BC can be used for F− removal from groundwater.
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