合作性
脆弱性
材料科学
放松(心理学)
环氧乙烷
离子
化学物理
氧化物
网络结构
聚合物
作者
Masaru Aniya,Masahiro Ikeda
出处
期刊:Materials Science Forum
日期:2022-04-25
卷期号:1059: 129-134
摘要
The understanding of fundamental materials properties is indispensable for the development of functional materials. Some years ago, it has been reported that the fragility in poly (ethylene oxide)-based Li + ion conductors decreases with the Li + ion content. The behavior was considered as unexpected and the origin unclear. In the present study, it is shown that the Bond Strength-Coordination Number Fluctuation (BSCNF) model of structural relaxation developed by the present authors provides an explanation to the observed behavior. The analysis based on the BSCNF model indicates that the cooperativity, or the number of correlated structural units involved in the network relaxation decreases with the Li + ion content.
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