Boosting peroxymonosulfate activation over Bi2MoO6/CuWO4 to rapidly degrade tetracycline: Intermediates and mechanism

Bi 2 MoO 6 /CuWO 4 exhibited excellent photodegradation activity with the presence of PMS demonstrating the successful fabrication of PMS/Vis catalytic system. • Enhanced visible light photocatalytic TC elimination over BMO/CWO(4:1) in Vis/PMS system. • BMO/CWO(4:1) maintained high photocatalytic activity at a wide pH range from 2.0 to 10.0. • The Cu 2+ /Cu + cycle was remarkably enhanced by the BMO/CWO(4:1) type-Ⅱ heterojunction. In peroxymonosulfate (PMS) activation processes, sluggish kinetics of Cu 2+ /Cu + redox rate has been the weakness of photocatalytic conversion efficiency. In this work, Bi 2 MoO 6 /CuWO 4 photocatalysts were synthesized via a facile hydrothermal method, which significantly boosted the Cu 2+ /Cu + cycle and promoted PMS activation for the removal of tetracycline (TC) under visible light irradiation. Bi 2 MoO 6 /CuWO 4 with the mass ratio of 4:1 displayed significantly enhanced photocatalytic activity toward TC degradation with the assistance of a low concentration of PMS, which was 1.95 and 2.24 times as those of CuWO 4 and Bi 2 MoO 6 , respectively. The influence of initial pH values, PMS dosage and different inorganic anions during the photodegradation process was systematically investigated and demonstrated that Bi 2 MoO 6 /CuWO 4 could perform photocatalytic reactions in the wide pH range of 2.0–10.0. Also, Bi 2 MoO 6 /CuWO 4 showed excellent reusability and stability in the cycling experiments. Additionally, the possible degradation pathways in the PMS system were proposed according to the determination of generated intermediates during the degradation process. According to the band structures together with active species trapping experiments, a possible type-Ⅱ photocatalytic charge transfer mechanism of Bi 2 MoO 6 /CuWO 4 was reasonably proposed. XPS analysis of the fresh and used samples indicated that constructing type-Ⅱ heterojunction significantly boosted the Cu 2+ /Cu + cycle and promoted PMS activation, thereby accelerating the TC degradation. In conclusion, this work could shed more light on promoting PMS activation for the practical removal of organic pollutants in wastewater.