Unbridged Rh(ii)–Rh(ii) complexes of N-heterocyclic carbenes and reactions with O2 to form dirhodium(μ–η1:η1-O2) complexes

Dimeric rhodium(ii) [Rh(L)(CH₃CN)]₂(PF₆)₄ and rhodium(iii) peroxide [Rh(L)(PPh₃)]₂(μ–η¹:η¹-O₂)(PF₆)₄ and [Rh(L)(PCy₃)]₂(μ–η¹:η¹-O₂)(PF₆)₄ (L = bis(N-pyridylimidazolylidenyl)methane) were reported.