化学
相对波动率
非随机双液模型
共沸蒸馏
萃取蒸馏
尿素
共晶体系
乙醇
共沸物
蒸馏
离子液体
焓
汽液平衡
有机化学
色谱法
活度系数
热力学
水溶液
催化作用
物理
合金
作者
Yong Peng,Xiuyang Lü,Baojian Liu,Jinjin Zhu
标识
DOI:10.1016/j.fluid.2017.03.010
摘要
The distillation of azeotropic mixtures is commonly and widely performed in the pharmaceutical, petroleum, and chemical industries. Deep eutectic solvents (DESs) are environmentally-friendly entrainers that have many properties similar to ionic liquids (ILs) but are also simple in preparation and cheap in price. Also, the ethanol/water system is a typical industrial azeotropic mixture. In this work, the relative volatility of ethanol and water at the azeotropic point was increased from 1.00 to 4.70 with 0–51.0 mass % ChCl/urea (1:2, mol/mol), with ChCl/urea showing a remarkable entrainer performance in this separation. Isobaric vapor–liquid equilibrium (VLE) data of four systems, water + ethanol, water + ChCl/urea, ethanol + ChCl/urea, and water + ethanol + ChCl/urea (at 10, 20, and 30 mass%), were determined using a modified Othmer equilibrium still at 101.32 kPa. After addition of ChCl/urea, the ethanol + water mixture's azeotropic point was eliminated. The parameters of the nonrandom two-liquid (NRTL) model for these systems were calculated and the predicted values for these systems were found to fit the experimental VLE data quite well.
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