A Dendrite‐Free Tin Anode for High‐Energy Aqueous Redox Flow Batteries

Metal-based aqueous redox flow batteries (ARFBs) such as zinc-based ARFBs have attracted remarkable attention owing to their intrinsic high energy density. However, severe dendrite issues limit their efficiency and lifespan. Here an aqueous metal anode operating between Sn(OH)₆ ^2- (stannate) and metal Sn is presented, providing a reversible four-electron transfer at -0.921 V vs standard hydrogen electrode. In strong contrast to severe Zn dendrites, the Sn(OH)₆ ^2- /Sn electrode shows smooth and dendrite-free morphology, which can be attributed to its intrinsic low-surface-energy anisotropy which facilitates isotropic crystal growth of Sn metal. By coupling with iodide/tri-iodide (I^- /I₃ ^- ), the static Sn-I cell demonstrates a stable cycling for 500 cycles (more than 2 months). In contrast, the state-of-the-art Zn anode suffers from serious dendrites and lasts less than 45 cycles (190 h) in Zn-I cells. A stable continuous flow cycling of Sn-I cell achieves a Sn areal capacity of 73.07 mAh cm^-2 at an average discharge voltage of 1.3 V for 350 h. The alkaline Sn electrode demonstrates dendrite-free morphology and superior performance in cycle life and areal capacity compared to state-of-the-art Zn metal anodes, offering a promising metal anode for high-energy ARFBs and other metal-based rechargeable aqueous batteries.