材料科学
石墨
阳极
复合数
三元运算
电极
电化学
复合材料
锂(药物)
化学工程
锂离子电池
电导率
电池(电)
化学
内分泌学
物理化学
工程类
功率(物理)
物理
程序设计语言
医学
量子力学
计算机科学
作者
Yan Wang,Li Zhang,Qunting Qu,Juan Zhang,Honghe Zheng
标识
DOI:10.1016/j.electacta.2016.01.025
摘要
Herein, a poly(vinylidene fluoride)-Polymethylmethacrylate-poly(lithium methacrylate) (PVDF-PMMA-PMALi) ternary composite binder is adopted for fabricating graphite porous electrode for the first time. The graphite anode with the optimized composite binder exhibits enhanced ionic conductivity, increased flexibility of the binder matrix and significantly improved electrochemical properties compared to that with pure PVDF binder. At a very high discharge rate of 50C, the graphite electrode with ternary binder still retains ca. 96.2% of its capacity while the electrode based on PVDF binder only delivers 16.2%. Additionally, high reversible capacity retentions are obtained to be 86.6, 50.1 and 21.9% of its reversible capacity at 0.1C at the same charge/discharge rates of 1C, 2C and 5C, respectively. These results enable us to get deep insight into the rational design of blended binder with interior synergistic effect for high-rate and long-life Li-ion battery anodes.
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