溶剂化
加速度
溶剂
动力学
化学
溶剂极性
化学物理
物理化学
计算化学
溶剂效应
热力学
有机化学
量子力学
经典力学
物理
作者
Lingqi Qiu,Zhenwei Wei,Honggang Nie,R. Graham Cooks
标识
DOI:10.1002/cplu.202100373
摘要
The kinetics of organic reactions of different types in microvolumes (droplets, thin films, and sealed tubes) show effects of gas/solution interfacial area, reaction molecularity and solvent polarity. Partial solvation at the gas/solution interface is a major contributor to the 104 -fold reaction acceleration seen in bimolecular but not unimolecular reactions in microdroplets. Reaction acceleration can be used to manipulate selectivity by solvent choice.
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