氮氧化物
水滑石
催化作用
化学
选择性
无机化学
吸附
硫黄
漫反射红外傅里叶变换
选择性催化还原
分解
扫描电子显微镜
化学工程
材料科学
物理化学
有机化学
光催化
工程类
复合材料
燃烧
作者
Yu Lyu,Gang Lyu,Yunqing Li,Bo Li,Ke Chen,Song Chen,Zhenguo Li,Suozhu Pan
出处
期刊:Chemosphere
[Elsevier]
日期:2022-10-01
卷期号:304: 135200-135200
被引量:1
标识
DOI:10.1016/j.chemosphere.2022.135200
摘要
The storage and reduction of NOx on a series of Fe-modified hydrotalcite-based lean NOx trap catalysts were assessed, together with the product selectivity. The crystal structures and micromorphologies of these materials were characterized using X-ray diffraction and scanning electron microscopy, while in situ diffuse reflectance Fourier transform infrared spectroscopy was used to evaluate the evolution of transition state species. The introduction of Fe was found to improve the synergistic interaction between the Mg and Fe in the hydrotalcite structure, allowing these catalysts to work efficiently at low temperatures. In addition, both Pt/BaO/MgAlO and Pt/BaO/MgFeO catalysts exhibited better NOx adsorption and reduction performance compared with Pt/BaO/Al2O3. The superior performance of the former two materials was attributed to the enhanced adsorption of NOx in the form of nitrates and nitrites by Fe and Mg and to the ready decomposition of these nitrates at low temperatures. A Pt/BaO/MgFeO catalyst showed excellent low temperature activity and high selectivity for N2 together with superior sulfur resistance compared with Pt/BaO/Al2O3.
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