Covalent organic frameworks based on tetraphenyl-p-phenylenediamine and metalloporphyrin for electrochemical conversion of CO2 to CO

The as-prepared TPPDA-CoPor-COF shows high CO faradic efficiencies of 87–90% from −0.6 to −0.9 V vs. RHE, and the largest CO partial current density of TPPDA-CoPor-COF exceeds most of reported COF-based electrocatalysts.