材料科学
共晶体系
烧结
陶瓷
粉煤灰
硅酸铝
化学工程
绿泥石
大气温度范围
复合数
活化能
煅烧
煤
矿物学
复合材料
冶金
相(物质)
微观结构
有机化学
催化作用
化学
热力学
物理
工程类
作者
Yingling Xiang,Linpei Han,Zhonghui Xu,Dan Hu,Liping Ning,Yunlin Yu,Shimin Gao,Chao Li,Jie Xu
标识
DOI:10.1016/j.ceramint.2023.05.093
摘要
This study presents the feasibility of preparing ceramic proppants (CPs) using drilling cuttings (DCs) and coal fly ash (CFA) via high-temperature sintering. The reaction behavior of barite in ceramic proppant precursors originating from DCs during the sintering process was investigated. The breakage ratio of the CPs (optimal group S3) met the requirements of Chinese standard SY/T 5108-2014 (2 K grade). The primary chemical reactions (7–8 in Table 4) between the barite and silica/alumina components resulted in a reduction of the eutectic point of the mixtures and the formation of aluminosilicates containing barium. However, these interactions also released gases (SO2 and O2), which created pores and weakened the CPs strength. The ideal temperature range for sintering is between 1170 and 1200 °C, during which there should be a gradual weight loss and minimal gas generation. This range will also ensure that the appropriate amount of liquid phase is present, which will have a moderate viscosity and aid in the densification of the ceramic proppants, as well as the formation of a dense enamel layer. The composite reactions of barite in the S3 sample follow a one-and-a-half-order chemical reaction mechanism within the temperature range of 950–1200 °C. The average activation energy and pre-exponential factor were 583.304 kJ mol−1 and 5.81 × 1020 min−1, respectively. The kinetic and reaction rate equations for the composite reactions were (1 − α)−1/2–1 = (5.81 × 1020 × e−5.83 × 10^5/RT) × t and dα/dt = (2(1 − α)3/2) × (5.81 × 1020 × e−(5.83 × 10^5)/RT)), respectively. This study provides a theoretical basis and guidelines for large-scale production of CPs using DCs and CFA.
科研通智能强力驱动
Strongly Powered by AbleSci AI