催化作用
烯烃纤维
微晶
产量(工程)
碳氢化合物
化学
碳化物
化学工程
碳纤维
材料科学
无机化学
有机化学
冶金
结晶学
复合材料
工程类
复合数
作者
Jingyu Chen,Seung Ju Han,Hae-Gu Park,Khasan Nasriddinov,Chun‐Dong Zhang,Ki‐Won Jun,Seok Ki Kim
标识
DOI:10.1016/j.apcatb.2023.122370
摘要
Although iron-based catalysts are effective for long-chain hydrocarbon formation during the hydrogenation of CO2, they easily undergo deactivation. Thus, the deactivation behaviors of Fe-based catalysts supported on active carbon were investigated using various promoters. Ten metals were selected as promoters, and the resulting catalytic activities and selectivities over the course of 100 h were evaluated. Catalyst deactivation was primarily caused by changes of active phase and active crystallite size, namely active site transitions. Although the oxidation of Fe carbide is an unavoidable process, this can be alleviated by increasing the crystallite size to expose greater numbers of active sites and compensate for the deactivation process. The Cu-modified catalyst exhibited the highest CO2 conversion and C5+ yield, but was easily deactivated. In contrast, the Zn-modified catalyst exhibited stable activity, good C5+ yield, and high olefin/paraffin ratio by inhibiting oxidation and exhibiting a large increase in the active crystallite.
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