Efficient and selective capture of various mercury species from water using an exfoliated thiocellulose

The primary challenge in mercury (Hg) adsorbents for large-scale practical applications is to achieve the balance between performance and economy. This work attempts to address this issue by synthesizing an exfoliated thiocellulose (CU-SH) with high thiol density and hierarchical porosity using in-situ ligands grafting combined with chemical stripping. The prepared CU-SH shows remarkable physical stability and chemical resistance, and the micron sized fiber is conducive to separation from water. Hg(II) adsorption tests in water demonstrate that CU-SH has broad working pH range (1−12), fast kinetics (0.64 g/(mg‧min)), high adsorption capacity (652.9 mg/g), outstanding selectivity (Kd = 6.2 × 106 mg/L), and excellent reusability (R > 95 % after 20 cycles). Importantly, CU-SH exhibits good resistance to various coexisting ions and organic matter, and can efficiently remove Hg(II) from different real water. CU-SH can be made into a Point of Use (POU) device for continuous and efficient removal of Hg(II) from drinking water. 0.1 g CU-SH filled device can purify 3.2 L of Hg(II) (0.5 ppm) contaminated tap water before the breakthrough point of 2 ppb. Moreover, CU-SH also reveals good adsorption affinity for Hg-dissolved organic matter complexes (Hg(II)-DOM) in water, chloro(phenyl)mercury (PMC) in organic media and Hg0 vapor in air, suggesting the great practical potential of CU-SH.