放射发光
发光
热释光
闪烁
分析化学(期刊)
Crystal(编程语言)
产量(工程)
材料科学
矿物学
化学
光学
物理
光电子学
探测器
色谱法
计算机科学
冶金
程序设计语言
作者
Warut Chewpraditkul,Prom Kantuptim,Marcin E. Witkowski,Michał Makowski,Winicjusz Drozdowski,Weerapong Chewpraditkul,Takayuki Yanagida
标识
DOI:10.1016/j.radphyschem.2023.110951
摘要
The luminescence and scintillation properties of Ce3+-doped Gd3(Al5-xScx)O12 (x = 1, 1.5, 2, 2.5, 3) garnet crystals grown by the floating zone method were investigated. With increasing Sc content, the Ce3+ 5d1 → 4f luminescence was blue shifted due to a decrease in 5d1-5d2 crystal field splitting (Δ12) of the 5de doublet state. The Sc content showed a strong influence on purity of garnet phase in the Gd3(Al5-xScx)O12:Ce crystals. The presence of secondary phase (perovskite and/or α-Al2O3) results to a poor transparency and a lower light yield (LY) value. The Gd3Al3Sc2O12:Ce crystal exhibited pure garnet phase, highest quantum yield (∼76 %) and transmittance (∼80 %), and highest LY value (6,850 photons/MeV at 662 keV γ rays) among the studied samples. Above RT, a decrease of radioluminescence (RL) yield occurs for all samples due to the thermal ionization process. A decrease of the RL yield at low temperature observed in correlation with the intense thermoluminescence peaks can be explained by the localization of electrons at intrinsic shallow traps.
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