非阻塞I/O
过电位
材料科学
电极
离解(化学)
铂金
氢
镍
吸附
化学工程
耐久性
复合材料
催化作用
电化学
化学
冶金
物理化学
有机化学
工程类
作者
Jingtong Zhang,Xiaodong Li,Xilin Zhang,Chuanqi Cheng,Liyang Xiao,Miao Zhou,Cunku Dong,Hui Liu,Xi‐Wen Du,Jing Yang
标识
DOI:10.1002/smtd.202300461
摘要
Abstract Highly active, durable, and cost‐effective electrodes for hydrogen evolution reaction (HER) at ultrahigh current densities (≥1 A cm −2 ) are extremely demanded for industrial high‐rate hydrogen production, but challenging. Here, a robust strongly coupled Ag(S)@NiO/nickel foam (NF) electrode is reported. Taking advantage of millisecond laser direct writing in liquid nitrogen technique, lattice‐matched and coherent interfaces are formed between Ag nanoparticles with stacking faults (denoted by Ag(S)) and NiO nanosheets, leading to strong interfacial electronic coupling, not only promoting H 2 O adsorption and dissociation on Ni 2+ but also enhancing H * adsorption on intrinsically inactive but most electrically conductive Ag. Strong chemical bonding is established at NiO/NF interface, guaranteeing rapid electron transfer and excellent mechanical durability under high‐rate hydrogen evolution. The physicochemically stable electrode achieves record‐low alkaline HER overpotential of 167 and 180 mV at 1 and 1.5 A cm −2 , respectively, along with negligible activity decay after 120 h test at ≈1.5 A cm −2 , surpassing reported non‐platinum group metal electrocatalysts.
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