化学
废止
组合化学
催化作用
过氧化物
过氧化苯甲酰
有机化学
聚合
聚合物
作者
Fang‐Lin Tan,Ming Hu,Ren‐Jie Song,Jin‐Heng Li
标识
DOI:10.1002/adsc.201700699
摘要
A new metal-free oxidative cascade methylation/cyclization of benzene-linked 1,7-enynes is described for the construction of methylated polyheterocyclic scaffolds skeletons. In this transformations, three new C-C bonds and two new rings were formed. Notably, di-tert-butyl peroxide (DTBP) acts not only a radical initiator but also an efficient methyl source.
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