碳纳米管
碳化
碳化物衍生碳
材料科学
催化作用
碳纤维
化学工程
氢
微型多孔材料
碳纳米管负载催化剂
甲烷
热解
碳纳米纤维
热解炭
介孔材料
分解
无机化学
纳米技术
化学
有机化学
复合材料
扫描电子显微镜
工程类
复合数
作者
Jingchao Yuan,Ying Wang,Mengfei Tang,Xiaodong Hao,Jun Li,Guojie Zhang,Yongfa Zhang
出处
期刊:Vacuum
[Elsevier]
日期:2023-01-01
卷期号:207: 111584-111584
被引量:7
标识
DOI:10.1016/j.vacuum.2022.111584
摘要
Activated carbon with a hierarchical micro/mesoporous carbon structure was synthesized using Shenmu coal as the raw material, which was impregnated with KOH (K) in different K/C ratios before carbonization at various temperatures. The obtained material was loaded with nickel and then employed as catalyst for the catalytic methane decomposition (CMD) to prepare carbon nanotubes. Using a constant nickel loading, the effects of the pore structure of the different activated carbon materials and hydrogen addition on the preparation of carbon nanotubes were investigated. The results show that the coal-based activated carbon with a micropore content of 0.8, synthesized at a carbonization temperature of 850 °C and a K/C ratio of 2, is the most suitable carrier for the methane cracking catalyst to produce carbon nanotubes. The diameter of the prepared carbon nanotubes is in the range of 50–120 nm with a length of 5–15 μm. The addition of hydrogen can prevent the high-temperature decomposition of oxygen-containing functional groups, and the activity of the catalyst can be maintained by inhibiting carbon deposition. Furthermore, the hydrogen present in the CMD process can promote the formation of carbon nanotubes with larger diameters (50–350 nm) and shapes. The nanotubes are more curved, and their length is reduced to 5–11 μm. Finally, the formation mechanism of carbon nanomaterials is discussed according to the morphological changes of the products after hydrogen addition and the existing theories. In conclusion, appropriate amounts of oxygen-containing functional groups and larger micropore volumes facilitate the pyrolysis of coal-based activated carbon catalysts in the preparation of carbon nanotubes.
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