Applications of vacancy defect engineering in persulfate activation: Performance and internal mechanism

The vacancy defects in heterogeneous catalysts have received extensive attention for persulfate (PS) activation. Vacancy defects can tune the electronic structure of metal oxides and generate unsaturated coordination sites. Meanwhile, the adsorption energy of reactants on catalyst surface is optimized. Thereby, the reaction energy barrier between catalysts and PS decreases, which could promote catalytic activation and accelerate pollutants degradation. Nowadays, oxygen vacancy (OV), nitrogen vacancy (NV), sulfur vacancy (SV), selenium vacancy (SeV) and titanium vacancy (TiV) have been widely studied with great potential for water remediation. So far, no review was reported regarding the vacancy activated persulfate systems. This paper summarized the types, preparation, mechanism and applications of vacancy in PS systems systematically. In addition, we put forward possible development of vacancy engineering in PS activation systems. It is expected that this review will contribute to the controllable synthesis and applications of vacancies in catalysts for PS activation and contaminants removal.